New paracyclophane phosphine for highly enantioselective ruthenium-catalyzed hydrogenation of prochiral ketones

DOI: 10.1055/s-2007-990917

Source and publish data:

Synthesis p. 3877 - 3885 (2007)

Update date:2022-07-30

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Authors:

Cheemala, Murthy N.

Gayral, Maud

Brown, John M.

Rossen, Kai

Knochel, Paul

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Article abstract of DOI:10.1055/s-2007-990917

The synthesis of a new paracyclophane phosphine is described. This ligand was highly efficient in the ruthenium-catalyzed asymmetric hydrogenation of various aromatic and heteroaromatic ketones. Georg Thieme Verlag Stuttgart.

Full text of DOI:10.1055/s-2007-990917

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Product name:(R)-4-bis(3,5-xylyl)phosphino-12-diphenylphosphino[2.2]paracyclophane

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