Alkylation and Oxidation of 6,7-Dihydro-6-methyl-5H-dibenzothiazocine. Selective Oxidation of the Sulfide Moiety by Transannular Participation of the Amino Group

DOI: 10.1246/bcsj.58.1946

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1946 - 1952 (1985)

Update date:2022-07-29

Topics:

Authors:

Ohkata, Katsuo

Takee, Kohichi

Akiba, Kin-ya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.58.1946

6,7-Dihydro-6-methyl-5H-dibenzo<1,5>thiazocine (7) was prepared by cyclization of the corresponding amino alcohol using thionyl chloride in acetonitrile.Methylation of 7 gave N,N-dimethyl derivative (8) as the sole product.Treatment of 7 with various

Full text of DOI:10.1246/bcsj.58.1946

Products guided by the article

Product name:2-(2-Chlorocarbonyl-phenylsulfanyl)-benzoic acid methyl ester

Cas No:100695-81-6

R&D Labs maybe for 100695-81-6

Shanghai Dynamic Industrial Co.,Ltd.

website:http://www.shdynamic.com

Contact:86-021 3392 6680

Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
Frapp's Chemical (NFTZ) Co.,Ltd

Contact:+86-576-86137892

Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Hefei Highzone Fine Chemical S&T CO.,LTD

Contact:86-0551-63663560

Address:room 1801 NO. 24 Shuguang RD.
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China

Relevant to this article

Gold(I) phosphine-decorated 2,2′:6′,2″-terpyridine ligands

Doi:10.1016/j.poly.2007.08.034
(2008)
Evaluation of several routes to advanced pregabalin intermediates: Synthesis and enantioselective enzymatic reduction using ene-reductases

Doi:10.1021/op4002774
(2014)
Uncharged water-soluble amide derivatives of pillar[5]arene: synthesis and supramolecular self-assembly with tetrazole-containing polymers

Doi:10.1007/s11172-020-2728-4
(2020)
Diastereoselective spiroannulation of phenolic substrates: Advances towards the asymmetric formation of the manumycin m-C₇N core skeleton

Doi:10.3390/12092215
(2007)
Conversion of Glutathione into Cadystins and Their Analogs Catalyzed by Carboxypeptidase Y

Doi:10.1271/bbb.60.1193
(1996)
An improved synthesis of 5-acylamino-6-oxo-2-phenyl-1(6h)-pyrimidineacetic acid from glycine with readily removable protecting groups

Doi:10.3987/COM-12-12518
(2012)

Article Doi