Alkylation and Oxidation of 6,7-Dihydro-6-methyl-5H-dibenzothiazocine. Selective Oxidation of the Sulfide Moiety by Transannular Participation of the Amino Group

DOI: 10.1246/bcsj.58.1946

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1946 - 1952 (1985)

Update date:2022-07-29

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Authors:

Ohkata, Katsuo

Takee, Kohichi

Akiba, Kin-ya

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Article abstract of DOI:10.1246/bcsj.58.1946

6,7-Dihydro-6-methyl-5H-dibenzo<1,5>thiazocine (7) was prepared by cyclization of the corresponding amino alcohol using thionyl chloride in acetonitrile.Methylation of 7 gave N,N-dimethyl derivative (8) as the sole product.Treatment of 7 with various

Full text of DOI:10.1246/bcsj.58.1946

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