Tetrahedron p. 3441 - 3452 (1987)
Update date:2022-08-04
Topics:
Djahanbini, Dariouche
Cazes, Bernard
Gore, Jaques
The esters of α-allenic alcohols, and particularly the phosphates, react in the presence of catalytic amounts of a palladium(O) complex with the anions of β-diesters, β-ketoesters and α-phenylsulfonylesters, leading by a direct substitution to β-difunctionalized allenes.This reaction can be applied to the fast obtention of an intermediate of the synthesis of the pheromone of dried bean beetle.
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