THE REGIOSELECTIVE EFFECT OF THE ALLYLIC SILICON OR OXYGEN ATOM IN 1,3-DIPOLAR CYCLOADDITION OF NITRONES

DOI: 10.1246/cl.1985.957

Source and publish data:

Chemistry Letters p. 957 - 960 (1985)

Update date:2022-08-04

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Authors:

Niwayama, Satomi

Dan, Shigeyuki

Inouye, Yoshinobu

Kakisawa, Hiroshi

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Article abstract of DOI:10.1246/cl.1985.957

1,3-Dipolar cycloaddition of nitrones on several allyl silanes, allyl ethers, and allyl alcohol was investigated.The silicon atom in dipolarophiles controlled the regioselectivity in favor for 5-(silylmethyl)isoxazolidines, while the oxygen atom for 4-(al

Full text of DOI:10.1246/cl.1985.957

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