THE REGIOSELECTIVE EFFECT OF THE ALLYLIC SILICON OR OXYGEN ATOM IN 1,3-DIPOLAR CYCLOADDITION OF NITRONES

DOI: 10.1246/cl.1985.957

Source and publish data:

Chemistry Letters p. 957 - 960 (1985)

Update date:2022-08-04

Topics:

Authors:

Niwayama, Satomi

Dan, Shigeyuki

Inouye, Yoshinobu

Kakisawa, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1985.957

1,3-Dipolar cycloaddition of nitrones on several allyl silanes, allyl ethers, and allyl alcohol was investigated.The silicon atom in dipolarophiles controlled the regioselectivity in favor for 5-(silylmethyl)isoxazolidines, while the oxygen atom for 4-(al

Full text of DOI:10.1246/cl.1985.957

Products guided by the article

Product name:(5-Methoxymethyl-4-methyl-2-phenyl-isoxazolidin-3-yl)-phenyl-methanone

Cas No:101161-28-8

R&D Labs maybe for 101161-28-8

SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Wuhan Jadechem International Trade Co.,Ltd.

website:http://www.jadechem-intl.com

Contact:+86-27-83527060

Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu

Relevant to this article

Synthesis of dehydroindolizidine-type poison-frog alkaloids via Michael-type conjugate addition

Doi:10.3184/174751917X14967701766987
(2017)
Directed ortho metalation reactions of aryl O-carbamates; a regiospecific synthesis of 2,2-disubstituted 2H-1-benzopyrans

Doi:10.1055/s-2001-9747
(2001)
Synthesis and structure of (η⁵-cyclohexadienyl)Mn(CO) ₃ and cationic (η⁶-arene)Mn(CO)₃ complexes comprising a double bond conjugated to the π system

Doi:10.1021/om7010672
(2008)
HIGH-YIELD SYNTHESES OF 2,3-DISUBSTITUTED FURANS AND THIOPHENES

Doi:10.1016/S0040-4039(00)98336-9
(1985)
Is Halogen-Lithium Exchange Intramolecularly Competitive with Removal of an Acidic Hydrogen? Reinvestigation of a Recent Claim

Doi:10.1021/ja00021a026
(1991)
Rh-catalyzed intermolecular and enantioselective [4 + 2] cycloaddition of 1,3-dienes with dimethyl acetylenedicarboxylate

Doi:10.1039/b717914f
(2008)

Article Doi