Tetrahedron Letters p. 3151 - 3154 (1985)
Update date:2022-07-29
Topics:
Hiemstra, Henk
Fortgens, Hendrikus P.
Stegenga, Sander
Speckamp, W. Nico
Intramolecular reactions of acyclic N-acyliminium ions with propargyl silanes,induced by protic or Lewis acid, lead to α-allenic amides or carbamates, i.e. derivatives of 3-vinylidene-pyrrolidine, 3-vinylidene-piperidine or 1-amino-2-vinylidenecyclopentane.
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