Rh(I)-catalyzed carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids leading to indenones

DOI: 10.1021/ja070107n

Source and publish data:

Journal of the American Chemical Society p. 5766 - 5771 (2007)

Update date:2022-07-30

Topics:

Authors:

Harada, Yasuyuki

Nakanishi, Jun

Fujihara, Hirokazu

Tobisu, Mamoru

Fukumoto, Yoshiya

Chatani, Naoto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja070107n

The Rh-catalyzed reaction of alkynes with 2-bromophenylboronic acids involves carbonylative cyclization to give indenones. The key steps in the reaction involve the addition of an arylrhodium(I) species to an alkyne and the oxidative addition of C-Br bond

Full text of DOI:10.1021/ja070107n

Products guided by the article

Product name:1-oxo-2-phenyl-1H-indene-3-carboxylic acid methyl ester

Cas No:101445-80-1

R&D Labs maybe for 101445-80-1

Shandong Jusage Technology Co.,Ltd.

Contact:86-13406130167

Address:No.20,North Ride No.9 Road, Guangrao Economic Development Zone, Shandong Province
Huaihua Baohua Biotechnology Co.,Ltd

website:http://www.baochengchem.com

Contact:86-519-82698291

Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020

Relevant to this article

Doi:10.1007/BF02959446
(1956)
Utilization of 1-Cyclobutenylphosphine Oxide as a 2-Phosphinyl-1,3-butadiene Synthon. Synthesis of Functionalized 1-Phosphinylcyclohexenes

Doi:10.1021/jo00362a010
(1986)
Synthesis and irreversible β-adrenergic blockade with a bromoacetamido derivative of betaxolol

Doi:10.1002/jps.2600741024
(1985)
Visible-light-driven photocatalytic activity of ZnO/g-C3N4 heterojunction for the green synthesis of biologically interest small molecules of thiazolidinones

Doi:10.1016/j.jphotochem.2020.112786
(2020)
Preparation and intramolecular [2+2]-photocycloaddition of 1,5-dihydropyrrol-2-ones and 5,6-dihydro-1H-pyridin-2-ones with C-, N-, and O-linked alkenyl side chains at the 4-position

Doi:10.1021/jo7027129
(2008)
Selective Baeyer-Villiger oxidation of racemic ketones in aqueous-organic media catalyzed by phenylacetone monooxygenase

Doi:10.1016/j.tetasy.2007.12.008
(2008)

Article Doi