REACTIONS OF trans-(Pt(H2)(P(C6H11)3)2) WITH HETEROCUMULENES. THE CRYSTAL AND MOLECULAR STRUCTURE OF trans-(Pt(P(C6H11)3)2(H9(OCH=C(C6H5)2))

Article abstract of DOI:10.1016/0022-328X(86)80014-6

Trans-PtH2(pCy3)2 (1) reacts with phenylisocyanate (2) and with diphenylketene (3) to yield the formamido complex (4) and the vinyloxo complex (5), respectively.The structure of 5 has been determined by X-ray diffraction.