CLEAVAGE OF VINYL CARBON-SILICON BOND WITH TETRABUTYLAMMONIUM FLUORIDE

DOI: 10.1016/S0040-4020(01)96677-3

Source and publish data:

Tetrahedron p. 3257 - 3268 (1985)

Update date:2022-07-30

Topics:

Authors:

Oda, Hiroji

Sato, Mitsuyoshi

Morizawa, Yoshitomi

Oshima, Koichiro

Nozaki, Hitoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96677-3

Dimethylphenylsilyl group is removed from a vinyl carbon with tetrabutylammonium fluoride.The presence of phenyl group on silicon atom plays a critical role.The cleavage of allyldimethylsilyl- and alkoxydimethylsilyl groups also proceeds very easily.

Full text of DOI:10.1016/S0040-4020(01)96677-3

Products guided by the article

Product name:5-Butyl-4-hexyl-2-methyl-2-phenyl-2,5-dihydro-[1,2]oxasilole

Cas No:101751-23-9

R&D Labs maybe for 101751-23-9

Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
Chengdu Yunyi International Trade Co., Ltd

Contact:

Address:china
Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China

Relevant to this article

Synthesis of (±)-likonide B (smenochromene D) using a regioselective Claisen rearrangement, separation of the enantiomers and stereochemical assignment

Doi:10.1039/b901358j
(2009)
INTRAMOLECULAR ELECTRON TRANSFER THROUGH ISOMERIC FORMS OF DICYANOBENZENE

Doi:10.1021/j100407a038
(1986)
5-(Halomethyl)-2-pyranones as irreversible inhibitors of α-chymotrypsin

Doi:10.1021/jm00158a027
(1986)
Spiro(indoline-3,4′-piperidine) growth hormone secretagogues as ghrelin mimetics

Doi:10.1016/S0960-894X(01)00324-9
(2001)
Mannich base derivatives of bioactive benzyl-1,3-benzodioxo-5-ols

Doi:10.1002/jhet.5570220412
(1985)
Synthesis of new substituted 5-methyl-3,5-diphenylimidazolidine-2,4-diones from substituted 1-(1-cyanoethyl-1-phenyl)-3-phenylureas

Doi:10.1002/jhet.5570420523
(2005)

Article Doi