CLEAVAGE OF VINYL CARBON-SILICON BOND WITH TETRABUTYLAMMONIUM FLUORIDE

DOI: 10.1016/S0040-4020(01)96677-3

Source and publish data:

Tetrahedron p. 3257 - 3268 (1985)

Update date:2022-07-30

Topics:

Authors:

Oda, Hiroji

Sato, Mitsuyoshi

Morizawa, Yoshitomi

Oshima, Koichiro

Nozaki, Hitoshi

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Article abstract of DOI:10.1016/S0040-4020(01)96677-3

Dimethylphenylsilyl group is removed from a vinyl carbon with tetrabutylammonium fluoride.The presence of phenyl group on silicon atom plays a critical role.The cleavage of allyldimethylsilyl- and alkoxydimethylsilyl groups also proceeds very easily.

Full text of DOI:10.1016/S0040-4020(01)96677-3

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