Tetrahedron Asymmetry p. 1903 - 1906 (1995)
Update date:2022-09-26
Topics:
Milton
Brand
Jones
Rayner
A novel enzymatic resolution of α-acetoxysulfides using Pseudomonas fluorescens lipase is reported. Selectivity is highly dependent on the substrate and solvent, with enantiomeric excesses of >95% in some cases. We believe these are the first examples of enzymatic resolutions of an S,O-acetal.
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