Enzymatic resolution of α-acetoxysulfides: A new approach to the synthesis of homochiral S,O-acetals

DOI: 10.1016/0957-4166(95)00248-N

Source and publish data:

Tetrahedron Asymmetry p. 1903 - 1906 (1995)

Update date:2022-09-26

Topics:

Authors:

Milton Milton

Brand Brand

Jones Jones

Rayner Rayner

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(95)00248-N

A novel enzymatic resolution of α-acetoxysulfides using Pseudomonas fluorescens lipase is reported. Selectivity is highly dependent on the substrate and solvent, with enantiomeric excesses of >95% in some cases. We believe these are the first examples of enzymatic resolutions of an S,O-acetal.

Full text of DOI:10.1016/0957-4166(95)00248-N

Products guided by the article

Product name:Ethylsulfanyl-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Cas No:1017994-52-3

R&D Labs maybe for 1017994-52-3

Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China

Relevant to this article

Novel highly potent μ-opioid receptor antagonist based on endomorphin-2 structure

Doi:10.1016/j.bmcl.2008.01.009
(2008)
Synthesis, determination of the lipophilicity, anticancer and antimicrobial properties of some fused 1,2,4-triazole derivatives

Doi:10.1016/j.ejmech.2007.03.033
(2008)
The class II/III transition electron transfer on an infrared vibrational time scale for N,Na?2-diphenyl- 1,4-phenylenediamine structures

Doi:10.1021/jp0492265
(2004)
Structural, photophysical, and catalytic properties of Au(I) complexes with 4-substituted pyridines

Doi:10.1021/ic701872f
(2008)
Variable density effect of self-assembled polarizable monolayers on the electronic properties of silicon

Doi:10.1021/ja077933g
(2008)
Synthesis, biological evaluation and molecular modeling study of 2-amino-3,5-disubstituted-pyrazines as Aurora kinases inhibitors

Doi:10.1016/j.bmc.2020.115351
(2020)

Article Doi