Enzymatic resolution of α-acetoxysulfides: A new approach to the synthesis of homochiral S,O-acetals

DOI: 10.1016/0957-4166(95)00248-N

Source and publish data:

Tetrahedron Asymmetry p. 1903 - 1906 (1995)

Update date:2022-09-26

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Authors:

Milton Milton

Brand Brand

Jones Jones

Rayner Rayner

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Article abstract of DOI:10.1016/0957-4166(95)00248-N

A novel enzymatic resolution of α-acetoxysulfides using Pseudomonas fluorescens lipase is reported. Selectivity is highly dependent on the substrate and solvent, with enantiomeric excesses of >95% in some cases. We believe these are the first examples of enzymatic resolutions of an S,O-acetal.

Full text of DOI:10.1016/0957-4166(95)00248-N

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