Regioselective Acylation of Glycols: Evidence for Organotin-mediated Reversal of Chemoselectivity

DOI: 10.1039/c39850001457

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Journal of the Chemical Society. Chemical communications p. 1457 - 1458 (1985)

Update date:2022-08-04

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Authors:

Ricci, Alfredo

Roelens, Stefano

Vannucchi, Alessio

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Article abstract of DOI:10.1039/c39850001457

Mono O-acylation of unsymmetrical diols via their dibutylstannyl derivatives takes place with high reversed chemoselectivity at the most substituted site, the reaction being complementary to standard methods.

Full text of DOI:10.1039/c39850001457

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