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Spontaneous Resolution of an Axially Dissymmetric 3-Carbamoylpyridinium Iodide; Intrinsic Discrimination between the Enatiomeric Forms by the Introduction of a Second Chiral Element

DOI: 10.1039/c39860000536

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 536 - 537 (1986)

Update date:2022-07-30

Topics:

Authors:

Bastiaansen, Loek A. M.Bastiaansen, Loek A. M.

Kanters, Jan A.Kanters, Jan A.

Steen, Fred H. van derSteen, Fred H. van der

Graaf, John A. C. deGraaf, John A. C. de

Buck, Henk M.Buck, Henk M.

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Article abstract of DOI:10.1039/c39860000536

The direction of the carbonyl-orientation in a solid amide-rotamer of 3-carbamoyl-1,2,4-trimethylpyridinium iodide is governed by the (R)-chirality in the amide side chain; structures, as determined by X-ray analysis and c.d

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Products guided by the article

Product name:N-benzyl-N-methyl-1,2,4-trimethyl-3-carbamoyl pyridinium iodide

Cas No:101948-10-1

101948-10-1

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