Inert Carbon Free Radicals. 7. "The (Kinetic) Reverse Effect" and Relevant Synthesis of New Monofunctionalized Triphenylmethyl Radicals and Their Nonradical Counterparts

DOI: 10.1021/jo00363a013

Source and publish data:

Journal of Organic Chemistry p. 2472 - 2480 (1986)

Update date:2022-08-04

Topics:

Authors:

Ballester, Manuel

Veciana, Jaime

Riera, Juan

Castaner, Juan

Rovira, Concepcion

Armet, Olga

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Article abstract of DOI:10.1021/jo00363a013

The high chemical passivity of the so-called "inert free radicals" (IFRs), particularly those derived from perchlorotriphenylmethyl (PTM), has allowed one to ascertain the kinetic influence of the free radical character on the reactivity of their nonradic

Full text of DOI:10.1021/jo00363a013

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