Bulletin of the Chemical Society of Japan p. 2366 - 2369 (1985)
Update date:2022-08-04
Topics: Purification and characterization Ring Expansion Functionalization of the Metacyclophanes Transannular Cyclization Yield Optimization and Scale-Up
Sato, Takeo
Nishiyama, Kozaburo
Morita, Akira
Iitaka, Yoichi
The treatment of <2.2>metacyclophanes with aluminum chloride gave a variety of hydropyrenes as the results of dehydrogenation, cycloisomerization, and disproportionation reactions.With ethylaluminum dichloride, however, a highly selective reaction occured to give trans-trans-1,2,3,3a,4,5,9,10,10a,10b-decahydropyrene.Revised structures were presented for cis-cis- and trans-trans-decahydropyrenes based on 13C NMR and X-ray crystallographic analyses.
View MoreChuzhou Baiao Biologhy S&T Co., Ltd.
Contact:+86-25-83212599;+86-25-83212699 13705185959
Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Contact:+86-10-59484199
Address:No.58-A1026 Liangguan Street
Guangzhou PI & PI Biotech Inc. Ltd.
Contact:+86-20-81716320
Address:Suite 501,198 Kaiyuan Ave.,Science City, Guangzhou,China
Hangzhou Ledun Technology Co.,Ltd.
Contact:86-571-18767088918
Address:No.6 street,XiaSha,Hangzhou,China.
website:http://www.coreychem.com
Contact:+86-371-86658258
Address:Building 10 of Innovation Park, East District of the National University Science Park
Doi:10.1021/ja01630a111
()Doi:10.1007/BF02157271
()Doi:10.1021/jo01362a023
(1957)Doi:10.1021/jo048768f
(2004)Doi:10.1002/jhet.5570450533
(2008)Doi:10.1021/om800195d
(2008)