Mercury in Organic Chemistry. 33. A Convenient Synthesis of Allenic and Propargylic Ketones via Acylation of Propargylic and Allenic Organomercurials, Respectively

DOI: 10.1021/jo00363a052

Source and publish data:

Journal of Organic Chemistry p. 2623 - 2624 (1986)

Update date:2022-08-03

Topics: Synthesis Acylation Ketones Convenient Allenic Propargylic

Authors:

Larock, Richard C.

Chow, Min-Shine

Smith, Sarah J.

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Article abstract of DOI:10.1021/jo00363a052

The low-temperature reaction of carboxylic acid chlorides, aluminum halides, and propargylic and allenic organomercurials affords the corresponding rearranged allenic and propargylic ketones, respectively, in high yields.The propargylic ketones rearrange

Full text of DOI:10.1021/jo00363a052

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