
Journal of Organic Chemistry p. 2623 - 2624 (1986)
Update date:2022-08-03
Topics: Synthesis Acylation Ketones Convenient Allenic Propargylic
Larock, Richard C.
Chow, Min-Shine
Smith, Sarah J.
The low-temperature reaction of carboxylic acid chlorides, aluminum halides, and propargylic and allenic organomercurials affords the corresponding rearranged allenic and propargylic ketones, respectively, in high yields.The propargylic ketones rearrange
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