Monatshefte fur Chemie p. 375 - 384 (1986)
Update date:2022-09-26
Topics:
Pindur, Ulf
Flo, Camran
The regioselective acylation of 2-methylindole (2) with acyclic di- and trialkoxycarbenium tetrafluoroborates 1 produces, by way of the stable indolyl-alkoxycarbenium ions 4, the 3-acylated indoles 5a-5c, and the 3-methoxycarbonylindole 5d.The ambident electrophilic cations 1 all react as a1-electrophiles with the very nucleophilic indole 2.In the reaction of 2 with trimethoxycarbenium tetrafluoroborate (2d) methylated products are formed additionally. - Keywords: 3-Acylated 2-methylindoles; Synthesis with di- and trialkoxycarbenium tetrafluoroborates
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