Kinetics of Thermolysis of Vinyl Azides. Empirical Rules for Formation of Azirines and Rearranged Nitriles

DOI: 10.1021/jo00366a019

Source and publish data:

Journal of Organic Chemistry p. 3176 - 3180 (1986)

Update date:2022-08-03

Topics:

Authors:

Hassner, Alfred

Wiegand, Norbert H.

Gottlieb, Hugo E.

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Article abstract of DOI:10.1021/jo00366a019

An evaluation of reported thermolyses of acyclic and cyclic vinyl azides R(N3)C=CR' leads to the empirical generalization that when R is aryl, alkyl, a heteroatom, or even alkoxycarbonyl, 1-azirines are usually formed upon thermolysis.When R is H or keto

Full text of DOI:10.1021/jo00366a019

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