Kinetics of Thermolysis of Vinyl Azides. Empirical Rules for Formation of Azirines and Rearranged Nitriles

DOI: 10.1021/jo00366a019

Source and publish data:

Journal of Organic Chemistry p. 3176 - 3180 (1986)

Update date:2022-08-03

Topics:

Authors:

Hassner, Alfred

Wiegand, Norbert H.

Gottlieb, Hugo E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00366a019

An evaluation of reported thermolyses of acyclic and cyclic vinyl azides R(N3)C=CR' leads to the empirical generalization that when R is aryl, alkyl, a heteroatom, or even alkoxycarbonyl, 1-azirines are usually formed upon thermolysis.When R is H or keto

Full text of DOI:10.1021/jo00366a019

Products guided by the article

Product name:Methanone, phenyl(2-phenyl-2H-azirin-3-yl)-

Cas No:102682-71-3

R&D Labs maybe for 102682-71-3

Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department

Contact:+86-29-88156413

Address:Jixiang Road 99 Xi'an Shaanxi Province
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36

Relevant to this article

Doi:10.1021/jm00205a007
(1978)
Synthesis and analysis of compounds having the skeleton of ergot alkaloids with the nitrogen atom in the D-ring transposed

Doi:10.1002/jhet.5570320435
(1995)
Synthesis of mono- and dihydroxylated furanoses, pyranoses, and an oxepanose for the preparation of natural product analogue libraries

Doi:10.1021/jo050558v
(2005)
Synthesis of thieno-fused heterocycles through reiterative iodocyclization

Doi:10.1002/adsc.201400072
(2014)
Metalation Chemistry of N-Ethyl-N-(1-methoxy-2,2-dimethylpropyl)benzamides). A New Protective Group for Secondary Amides

Doi:10.1021/jo00131a020
(1995)
N-Metalated imines by reaction of 1,1-diethoxybut-2-ene with aromatic nitriles, as useful intermediates for the synthesis of substituted pyrimidines and cyclopentenones

Doi:10.1039/b719462e
(2008)

Article Doi