A synthetic approach to Benanomicin A. 2. Synthesis of the substituted 5,6-dihydrobenzo[a]naphthacenequinone

DOI: 10.7164/antibiotics.50.755

Source and publish data:

Journal of Antibiotics p. 755 - 764 (1997)

Update date:2022-08-04

Topics:

Authors:

Nishizuka, Toshio

Hirosawa, Sehei

Kondo, Shinichi

Ikeda, Daishiro

Takeuchi, Tomio

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Article abstract of DOI:10.7164/antibiotics.50.755

The key intermediate tri-substituted α-tetralone (8) has been synthesized, either via tandem MICHAEL addition-DIECKMANN condensation reaction between dienolate and methyl crotonate in a low yield or via BARTON'S radical decarboxylation of diester (9) with

Full text of DOI:10.7164/antibiotics.50.755

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