Chemistry Letters p. 1583 - 1586 (1985)
Update date:2022-08-04
Topics:
Tanikaga, Rikuhei
Konya, Naoto
Kaji, Aritsune
The amine-catalyzed Knoevenagel reactions of aldehydes and active methylene compounds containing two activating groups were found to involve many reversible steps, and the diastereomeric intermediary condensation compounds yielded thermodynamically stable products via carbanionic intermediates stablized and sterically affected by two activating groups.
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Doi:10.1021/jo01080a002
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