THE RELATIVE STABILITY OF ALLYL ETHER, ALLYLOXYCARBONYL ESTER AND PROP-2 ENYLIDENE ACETAL, PROTECTIVE GROUPS TOWARD IRIDIUM, RHODIUM AND PALLADIUM CATALYSTS.

DOI: 10.1016/S0040-4039(01)80849-2

Source and publish data:

Tetrahedron Letters p. 5045 - 5048 (1985)

Update date:2022-08-05

Topics:

Authors:

Kloosterman, M

Boom, J. H. Van

Chatelard, P.

Boullanger. P.

Descotes, G.

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Article abstract of DOI:10.1016/S0040-4039(01)80849-2

The deprotection of allyloxycarbonyl derivatives of sugars was realized in the presence of allylether or prop-2-enylidene acetal with Pd(PPh3)4 or RhCl(PPh3)3 as catalyst while PF6 isomerized selectively the allyl ethers.

Full text of DOI:10.1016/S0040-4039(01)80849-2

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