Tetrahedron Letters p. 6203 - 6206 (1994)
Update date:2022-08-05
Topics:
Vasapollo, Giuseppe
Somasunderam, Anoma
Ali, Bassam El
Alper, Howard
Di-, and trisubstituted 1,3-dienes are converted to γ,δ-unsaturated acids by use of formic acid, carbon monoxide, and catalytic quantities of Pd-C/PPh3/Ph2P(CH2)4PPh2 in 1,2-dimethoxyethane.A β,γ-unsaturated acid was obtained when the monosubstituted diene, isoprene, was used as the reactant.
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