Tetrahedron p. 1169 - 1178 (1986)
Update date:2022-07-30
Topics:
Guinamant, J. L.
Robert, A.
Contrary to the reaction of gem dicyano epoxides with thiocarbonyl binucleophilic reagents, nitrogen binucleophilic reagents react in a first step with one nitrile group of the epoxides.The reaction leads to enaminoimidazoles.The two carbons of the epoxides act as potential electrophilic centers when these epoxides are reacted with halohydrates of nitrogen binucleophilic reagents.The reaction is a one pot selective synthesis of imidazoles and condensed imidazoles.
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