Chemoenzymatic synthesis of trans-4,5-dihydroxycyclopent-2-enones: Conversion to D-1-deoxynojirimycin

DOI: 10.1039/c39950001139

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1139 - 1140 (1995)

Update date:2022-07-30

Topics:

Authors:

Johnson Johnson

Nerurkar

Golebiowski

Sundram Sundram

Esker Esker

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Article abstract of DOI:10.1039/c39950001139

(4R,5S)-trans-4,5-Bis(tert-butyldimethylsilyloxy)cyclopent-2-enone 8 and (4R,5S)-trans-4,5-di(benzyloxy)cyclopent-2-enone 20 are prepared by equilibration of the corresponding cis derivatives; enone 8 is transformed into the glucosidase inhibitor, D-1-deoxynojirimycin 14.

Full text of DOI:10.1039/c39950001139

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