Angewandte Chemie - International Edition p. 7887 - 7891 (2005)
Update date:2022-08-03
Topics:
Hagen, Volker
Dekowski, Brigitte
Nache, Vasilica
Schmidt, Reinhard
Geissler, Daniel
Lorenz, Dorothea
Eichhorst, Jenny
Keller, Sandra
Kaneko, Hiroshi
Benndorf, Klaus
Wiesner, Burkhard
(Chemical Equation Presented) Shedding light: Efficient activation of cyclic nucleoside monophosphates (cNMPs) can be achieved upon one- and two-photon flash photolysis of novel photolabile coumarinylmethyl esters of cAMP and cGMP (A = adenosine, G = guanosine) as well as their 8-bromosubstituted derivatives. The phototriggers show high solubility in water and permit space- and time-resolved investigations of the molecular mechanisms of cyclic nucleotide dependent processes.
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