Chemistry Letters p. 859 - 862 (1983)
Update date:2022-08-03
Topics:
Takahashi, Kazumasa
Shibasaki, Kenichiro
Ogura, Katsuyuki
Iida, Hirotada
An efficient sequence proposed for the conversion of esters to α-keto amides involves the reaction of α-(N-methylanilino)-acetonitrile with esters to afford β0hydroxy-α-cyanoenamines of which hydrolysis using copper (II) acetate gives the corresponding α-keto amides in good yields.
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