AN EFFICIENT SYNTHESIS OF α-F-ALKYNYLATED ALCOHOLS BY NEW SILOXANE-FLUORIDE ION CATALYZED REACTION OF 1H-F-1-ALKENEPHOSPHONATES WITH ALDEHYDES

DOI: 10.1016/S0040-4039(00)84018-6

Source and publish data:

Tetrahedron Letters p. 357 - 360 (1986)

Update date:2022-08-04

Topics: Aldehydes Fluoride ion Siloxane

Authors:

Ishihara, Takashi

Maekawa, Takashige

Ando, Teiichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84018-6

1H-F-1-Alkenephosphonates react smoothly with a variety of aldehydes under the influence of catalytic amounts of hexamethyldisiloxane and tetrabutylammonium fluoride at room temperature to afford the corresponding α-F-alkynylated alcohols in good to excel

Full text of DOI:10.1016/S0040-4039(00)84018-6

Products guided by the article

Product name:6,6,7,7,7-Pentafluoro-2-phenyl-hept-4-yn-3-ol

Cas No:103245-52-9

R&D Labs maybe for 103245-52-9

Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands

Relevant to this article

Heterolysis of NH-indoles by bifunctional amido complexes and applications to carboxylation with carbon dioxide

Doi:10.1021/om500695a
(2014)
Total synthesis and structure assignment of papuamide B, A potent marine cyclodepsipeptide with anti-HIV properties

Doi:10.1002/anie.200705557
(2008)
Stereoselective and Regioselective Thermal and Photochemical Preparation of Siloxy Dienes

Doi:10.1021/jo00367a015
(1986)
Design, Structure-Activity, and Molecular Modeling Studies of Potent Renin Inhibitory Peptides Having N-Terminal Nⁱⁿ-For-Trp (Ftr): Angiotensinogen Congeners Modified by P₁-P₁' Phe-Phe, Sta, LeuΨVal or LeuΨVal Substitutions

Doi:10.1021/jm00396a006
(1988)
Chemoenzymatic synthesis of l-tyrosine derivative for a transketolase assay

Doi:10.1016/j.tetlet.2008.03.099
(2008)
Selenium-containing heterocycles: Synthesis and pharmacological activities of some new 4-methylquinoline-2(1H) selenone derivatives

Doi:10.1002/ardp.200700202
(2008)

Article Doi