AN EFFICIENT SYNTHESIS OF α-F-ALKYNYLATED ALCOHOLS BY NEW SILOXANE-FLUORIDE ION CATALYZED REACTION OF 1H-F-1-ALKENEPHOSPHONATES WITH ALDEHYDES

DOI: 10.1016/S0040-4039(00)84018-6

Source and publish data:

Tetrahedron Letters p. 357 - 360 (1986)

Update date:2022-08-04

Topics: Aldehydes Fluoride ion Siloxane

Authors:

Ishihara, Takashi

Maekawa, Takashige

Ando, Teiichi

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Article abstract of DOI:10.1016/S0040-4039(00)84018-6

1H-F-1-Alkenephosphonates react smoothly with a variety of aldehydes under the influence of catalytic amounts of hexamethyldisiloxane and tetrabutylammonium fluoride at room temperature to afford the corresponding α-F-alkynylated alcohols in good to excel

Full text of DOI:10.1016/S0040-4039(00)84018-6

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