REACTION OF 1-PHENYLDIAZOETHANE WITH TETRACHLORO-p- AND o-BENZOQUINONES

DOI: 10.1016/S0040-4039(00)95026-3

Source and publish data:

Tetrahedron Letters p. 5317 - 5318 (1985)

Update date:2022-09-26

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Authors:

Oshima, Takumi

Nagai, Toshikazu

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Article abstract of DOI:10.1016/S0040-4039(00)95026-3

Reaction of 1-phenyldiazoethane(1) with tetrachloro-p-benzoquinone(2) gave 1-alkoxy-4-ethenyloxy-tetrachlorobenzene(4).With tetrachloro-o-benzoquinone(5), 1 provided 1-alkoxy-2-ethenyloxy-tetrachlorobenzene(7) and tetrachlorobenzo-1,3-dioxolane(8).The mechanism and the effect of added methanol were discussed.

Full text of DOI:10.1016/S0040-4039(00)95026-3

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