HFe(CO)4-, a versatile reagent toward chlorophosphines. Facile synthesis of new phosphorus transition-metal complexes

DOI: 10.1021/om00140a031

Source and publish data:

Organometallics p. 1914 - 1916 (1986)

Update date:2022-07-29

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Authors:

Mathieu, René

Caminade, Anne-Marie

Majoral, Jean-Pierre

Attali, Serge

Sanchez, Michel

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Article abstract of DOI:10.1021/om00140a031

Depending on the experimental conditions, reaction of [Ph₄P][HFe(CO)₄] (1) with phenyldichlorophosphine leads quantitatively either to the stable secondary halophosphine complex PhP(H)ClFe(CO)₄ (2b), or to the first nonhin

Full text of DOI:10.1021/om00140a031

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Product name:(P(C₆H₅))2{Fe(CO)4}2

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