Tetrahedron Letters p. 4965 - 4968 (1985)
Update date:2022-08-04
Topics: Reagent Selective Versatile Experimental terms Generation
Wozniak, L.
Kowalski, J.
Chojnowski, J.
Bis(trimethylsilyl)peroxide, Me3SiOOSiMe3, (BSPO) oxidizes phosphines and phosphites to respective oxyphosphoryl derivatives with retention of the configuration at the phosphorus atom.It also converts thiophosphoryl function to oxyphosphoryl function with inversion of the configuration at phosphorus.High yields and high stereoselectivities of these processes render them useful for the synthetic application.
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Doi:10.1016/0022-328X(85)80276-X
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(2015)Doi:10.1080/00397911.2015.1135954
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(2001)Doi:10.1016/j.bmcl.2007.11.093
(2008)
