OXOMANGANESE(IV) PORPHYRINS IDENTIFIED BY RESONANCE RAMAN AND INFRARED SPECTROSCOPY: WEAK BONDS AND THE STABILITY OF THE HALF-FILLED T2g SUBSHELL.

Article abstract of DOI:10.1021/ja00221a010

The Mn**I**V-O stretching frequency is identified at 754 cm** minus **1 in resonance Raman (RR) and infrared (IR) spectra of Mn**I**V porphyrins prepared by electrooxidation of ClMn**I**I**ITMP, ClMn**I**I**ITPP and ClMn**I**I**IOEP in CH//3CN containing