CARDIAC GLYCOSIDES: 5. STEREOSELECTIVE SYNTHESES OF DIGITOXIGENIN α-D, β-D, α-L AND β-L-GLUCOSIDES

Article abstract of DOI:10.1016/S0040-4020(01)91342-0

As part of a continuing study of cardiac glycosides, stereoselective syntheses of the four possible glucosides of digitoxigenin were developed via the thermodynamically produced tetra-O-benzyl-D- and L-glucosyl α-trichloroacetaimidates 2α and 11α, and the