
Journal of the Chemical Society. Chemical communications p. 388 - 390 (1986)
Update date:2022-09-26
Topics:
Butenschoen, Holger
Winkler, Matthias
Vollhardt, K. Peter C.
(η5-C5H5)Co(CO)2 catalyses the <2 + 2+ 2> cycloaddition of silylated enediynes to furnish 1-trimethylsilyl and 1,11-bis(trimethylsilylated) A-ring aromatic steroids which exhibit unexpected hindered rotation of the trimethylsilyl groups.
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Doi:10.1021/jo00373a027
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