SYNTHESIS OF CHIRAL 1,2-DIOLS AND RELATED COMPOUNDS OF BIOLOGICAL ACTIVITIES VIA STEPWISE RING FISSION OF 5-ALKYL-6,8-DIOXABICYCLOOCTANE SKELETON

DOI: 10.1016/S0040-4039(00)83984-2

Source and publish data:

Tetrahedron Letters p. 231 - 234 (1986)

Update date:2022-08-05

Topics:

Authors:

Masaki, Yukio

Serizawa, Yuzuru

Nagata, Kinnosuke

Oda, Hirohisa

Nagashima, Hiromu

Kaji, Kenji

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Article abstract of DOI:10.1016/S0040-4039(00)83984-2

5-Alkyl-7-mesyloxymethyl-6,8-dioxabicyclo<3.2.1>octanes, prepared from (+)-tartaric acid, were converted by means of an organoaluminium reagent Et₂AlSPh into the pyranoid monothioacetals, which were utilized via the successive thioacetalization

Full text of DOI:10.1016/S0040-4039(00)83984-2

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