Crown-shaped Tetrametallic Imidoyl Complexes of Palladium. X-Ray Crystal Structure of 2>(μ-Cl)(μ-MeCO2)>2>

DOI: 10.1039/DT9860000259

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 259 - 264 (1986)

Update date:2022-07-30

Topics:

Authors:

Uson, Rafael

Fornies, Juan

Espinet, Pablo

Lalinde, Elena

Garcia, Augustin

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9860000259

The complexes <<1>2>(μ-X¹)(μ-X²)>n> (R¹=Me or p-tolyl; X¹=X²=Cl) and their derivatives (X¹=Cl, X²=MeCO2 or CF3CO2; X¹=X²=MeCo2 or CF3CO2), obtained by metathetical reactions with the corresponding silver salts, are shown to be tetrametallic (n=2) by molecular-weight determinations.Their structures are discussed on the basis of (1)H and (19)F n.m.r. data.The crystal structure of the title complex has been solved by X-ray diffraction methods 1/n, a=14.380(4), b=19.980(4), c=15.976(4) Angstroem, β=103.51(3) deg, Z=4, R'=0.046 for 5428 unique observed reflections>.The tetrametallic mo lecule is crown-shaped.The bond lenghts at palladium reflect the strong trans influence of the imidoyl-C atom; the Pd-Cl bonds trans to C are amongst the longest known.

Full text of DOI:10.1039/DT9860000259

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[((Pd₂(C(C₆F₅)NCH₃)2)(CH₃CO₂)2)2]

Cas No:104166-98-5

R&D Labs maybe for 104166-98-5

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Landz International Company Ltd.

Contact:0086-21-58891610

Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing

Relevant to this article

Convenient method for the preparation of heterodialkyl-H-phosphonates from diphenyl-H-phosphonate

Doi:10.1080/00397910801982282
(2008)
Synthesis and reactions of 5-amino-3-(3-methyl-5-oxo-1-phenyl-2-pyrazolin- 4-yl)-7-phenyl-7H-thiazolo[3,2-a]pyrimidine-6-carbonitrile

Doi:10.1007/s00706-007-0703-5
(2007)
Application and developing of iron-doped multi-walled carbon nanotubes (Fe/MWCNTs) as an efficient and reusable heterogeneous nanocatalyst in the synthesis of heterocyclic compounds

Doi:10.1002/aoc.4124
(2018)
STEREOSELECTIVE FORMATION OF A HYDRINDANE RING SYSTEM BY ANIONIC OLEFIN CYCLIZATION. TRAPPING OF THE ALKYLLITHIUM INTERMEDIATE WITH ELECTROPHILES.

Doi:10.1016/S0040-4039(00)84037-X
(1986)
3-NITROCYCLOALKENONES, SYNTHESIS AND USE AS REVERSE AFFINITY CYCLOALKYNONE EQUIVALENTS

Doi:10.1016/S0040-4039(01)92500-6
(1981)
Organocatalytic Kinetic Resolution of Sulfoximines

Doi:10.1021/jacs.6b00143
(2016)

Article Doi