Tetrahedron Letters p. 4203 - 4206 (1999)
Update date:2022-07-30
Topics: Regioselectivity Column chromatography Yield Chiral center Recrystallization Catalytic hydrogenation Stereoselective synthesis Enantiomers Optical rotation Stereoisomers HPLC (high-performance liquid chromatography) Protecting group Diastereomers Retrosynthetic analysis Chiral Resolution Coupling Reaction Oxazolidinone Cytoxazone NMR spectroscopy (Nuclear Magnetic Resonance)
Sakamoto, Yasuharu
Shiraishi, Akiko
Seonhee, Jeong
Nakata, Tadashi
Cytoxazone, a novel cytokine modulator, and its stereoisomers were stereoselectively synthesized via stereocontrolled introduction of an azide group and direct construction of the 2-oxazolidinone ring from an azide carbonate by reductive cyclization.
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Doi:10.1007/s00706-007-0703-5
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(2018)Doi:10.1016/S0040-4039(00)84037-X
(1986)Doi:10.1016/S0040-4039(01)92500-6
(1981)Doi:10.1021/jacs.6b00143
(2016)Doi:10.1007/BF01152328
(1980)
