Mild Reductive Cleavage of α-Aminoethers

DOI: 10.1002/ardp.19863190805

Source and publish data:

Archiv der Pharmazie p. 694 - 704 (1986)

Update date:2022-07-29

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Authors:

Lee, Dong Ung

Wiegrebe, Wolfgang

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Article abstract of DOI:10.1002/ardp.19863190805

1,2,3,4-Tetrahydro-6,7-dimethoxy-2-methylisoquinoline (1) is converted by ethyl chloroformate (ECF)/NaBH3CN to 2-<β-(N-ethoxycarbonyl-N-methyl)aminoethyl>-4,5-dimethoxytoluene (4) via the quaternary urethane 2.The same procedure leads from laudanosine (5)

Full text of DOI:10.1002/ardp.19863190805

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