UNUSUAL REACTION OF 2-TRIMETHYLSILYLETHYLIDENETRIARYLPHOSPHORANES (SEYFERTH-WITTIG REAGENT) WITH α-METHYLALDEHYDES: A NOVEL METHOD FOR HIGHLY CRAM-DIASTEREOSELECTIVE ADDITION OF VINYL ANION EQUIVALENT

DOI: 10.1016/S0040-4039(00)88933-9

Source and publish data:

Tetrahedron Letters p. 4471 - 4474 (1985)

Update date:2022-08-04

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Authors:

Tsukamoto, Masamitsu

Iio, Hideo

Tokoroyama, Takashi

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Article abstract of DOI:10.1016/S0040-4039(00)88933-9

By the reaction of α-methylaldehydes with trimethylsilylethylidenetriarylphosphoranes the introduction of vinyl group is effected in highly Cram-selective manner.

Full text of DOI:10.1016/S0040-4039(00)88933-9

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