Tetrahedron p. 4727 - 4738 (1985)
Update date:2022-08-02
Topics: Secondary amine Reaction Primary Amine Experimental study studies Phenylseleninic anhydride Phenylseleninic acid
Barton, Derek H. R.
Lusinchi, Xavier
Milliet, Pierre
The dehydrogenation under mild conditions of indolines with phenylseleninic anhydride or acid affords good yields of indoles or of 3-phenylselenenyl indoles.Tetrahydroquinoline and -isoquinoline show comparable behaviour.The dehydrogenation of primary amines gives more complicated mixtures from which nitriles and bis-2-phenylselenenylaldehydes can be isolated.
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