Tetrahedron Letters p. 3525 - 3528 (1996)
Update date:2022-08-04
Topics:
Eames, Jason
Warren, Stuart
The factors controlling the stereospecific cyclisation of 1,3-diols with PhS migration to give THFs rather than oxetanes are reassessed in the light of evidence that these reactions are under thermodynamic control. Rearrangement of cyclic sulfites gives the nearest approach to kinetic control.
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