HIGHLY STEREOSELECTIVE ALDOL-TYPE REACTION OF CHIRAL TIN (II) ENOLATE. FORMAL TOTAL SYNTHESIS OF (+/-)-THIENAMYCIN

DOI: 10.1246/cl.1986.637

Source and publish data:

Chemistry Letters p. 637 - 640 (1986)

Update date:2022-07-29

Topics:

Authors:

Iwasawa, Nobuharu

Mukaiyama, Teruaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1986.637

Highly efficient internal chiral induction is achieved in the aldol-type reaction of thin (II) enolate generated from 3-amino-substituted butanoylthiazolidine-2-thione.This reaction is successfully applied to the formal total synthesis of (+/-)-thienamyci

Full text of DOI:10.1246/cl.1986.637

Products guided by the article

Product name:Benzyl-[(1S,2R)-2-((R)-hydroxy-phenyl-methyl)-1-methyl-3-oxo-3-(2-thioxo-thiazolidin-3-yl)-propyl]-carbamic acid tert-butyl ester

Cas No:104862-57-9

R&D Labs maybe for 104862-57-9

Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,

Relevant to this article

Photoresponsive peptoid oligomers bearing azobenzene side chains

Doi:10.1039/b804802a
(2008)
Synthesis of N-allylideneamines and their use for the double nucleophilic addition of ketene silyl (thio)acetals and trimethylsilyl cyanide

Doi:10.1021/ol8014539
(2008)
Selectively Protected L-Dopa Derivatives: Application of the Benzylic Hydroperoxide Rearrangement

Doi:10.1021/jo00232a044
(1987)
Development of potent and selective inhibitors of ecto-5′- nucleotidase based on an anthraquinone scaffold

Doi:10.1021/jm901851t
(2010)
Titanium mediated asymmetric aldol reaction with α-fluoropropionimide enolates

Doi:10.1016/j.jfluchem.2007.05.012
(2007)
Synthesis and characterization of new ^99mTc-radiopharmaceuticals with dithiobenzoate derivatives for the study of septic inflammatory processes

Doi:10.1002/jlcr.673
(2003)

Article Doi