HIGHLY STEREOSELECTIVE ALDOL-TYPE REACTION OF CHIRAL TIN (II) ENOLATE. FORMAL TOTAL SYNTHESIS OF (+/-)-THIENAMYCIN

DOI: 10.1246/cl.1986.637

Source and publish data:

Chemistry Letters p. 637 - 640 (1986)

Update date:2022-07-29

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Authors:

Iwasawa, Nobuharu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1986.637

Highly efficient internal chiral induction is achieved in the aldol-type reaction of thin (II) enolate generated from 3-amino-substituted butanoylthiazolidine-2-thione.This reaction is successfully applied to the formal total synthesis of (+/-)-thienamyci

Full text of DOI:10.1246/cl.1986.637

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