ASYMMETRIC DIELS-ALDER REACTION BETWEEN THE CHIRAL ISOPRENE UNITS 2-(R)-AND (S)-BENZYLOXY-2,5-DIHYDRO-4-FURANCARBOXALDEHYDE AND CYCLOPENTADIENE

DOI: 10.1016/S0040-4039(01)80899-6

Source and publish data:

Tetrahedron Letters p. 5605 - 5608 (1985)

Update date:2022-08-03

Topics:

Authors:

Sundin, Anders

Frejd, Torbjoern

Magnusson, Goeran

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Article abstract of DOI:10.1016/S0040-4039(01)80899-6

The title Diels-Alder reaction gave a mixture of enantiomerically pure adducts with complete norbornane-type monoterpene skeletons.The exo/endo ratio of the products changed from approximately 4:1 at 5 deg to 2:1 at 165 deg.

Full text of DOI:10.1016/S0040-4039(01)80899-6

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