Journal of the American Chemical Society p. 8032 - 8039 (1986)
Update date:2022-09-26
Topics:
Paquette, Leo A.
Varadarajan, Aravamuthan
Burke, Lonnie D.
Seven 1-substituted 6-methoxybenzonorbornadienes were prepared and subjected to acetophenone-senzitized photoisomerization.In the -COOCH3, -CONH2, -COCH3, and -CN examples, the excited-state 1,2-aryl shift was overwhelmingly controlled by the bridgehead s
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