Triplet Photoisomerization of 1-Substituted 6-Methoxybenzonorbornadienes. Excited-State Competition between Bridgehead and m-Methoxy Groups for Intramolecular Control of the Dual Channel Di-?-methane Pathway. The Vinyl Deuterium Isotope Effect

DOI: 10.1021/ja00285a026

Source and publish data:

Journal of the American Chemical Society p. 8032 - 8039 (1986)

Update date:2022-09-26

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Authors:

Paquette, Leo A.

Varadarajan, Aravamuthan

Burke, Lonnie D.

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Article abstract of DOI:10.1021/ja00285a026

Seven 1-substituted 6-methoxybenzonorbornadienes were prepared and subjected to acetophenone-senzitized photoisomerization.In the -COOCH3, -CONH2, -COCH3, and -CN examples, the excited-state 1,2-aryl shift was overwhelmingly controlled by the bridgehead s

Full text of DOI:10.1021/ja00285a026

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