REACTIONS OF (ARENE)TRICARBONYLCHROMIUM STABILIZED CARBOCATIONS WITH AROMATICS AND β-DICARBONYL COMPOUNDS

DOI: 10.1016/0022-328X(86)84039-6

Source and publish data:

Journal of Organometallic Chemistry p. 119 - 126 (1986)

Update date:2022-08-02

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Authors:

Uemura, Motokazu

Minami, Tatsuya

Hayashi, Yuji

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Article abstract of DOI:10.1016/0022-328X(86)84039-6

Primary and secondary benzylic carbocations, stabilized by a tricarbonylchromium group, gave coupling products with several aromatics or β-dicarbonyl compounds in good yield and this reaction presents a new synthetic method for carbon-carbon bond formation.The chromium complexes of tertiary benzyl alcohols gave dehydrated products without carbon-carbon coupling products under similar conditions.

Full text of DOI:10.1016/0022-328X(86)84039-6

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