APPLICATION OF SELENOSULFONATION TO MARINE STEROL SYNTHESIS. PREPARATION OF 24,28-DEHYDROAPLYSTEROL, XESTOSTEROL AND OSTREASTEROL FROM A COMMON ACETYLENIC INTERMADIATE

DOI: 10.1016/S0040-4039(00)84483-4

Source and publish data:

Tetrahedron Letters p. 2187 - 2190 (1986)

Update date:2022-07-30

Topics:

Authors:

Back, Thomas G.

Proudfoot, John R.

Djerassi, Carl

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Article abstract of DOI:10.1016/S0040-4039(00)84483-4

The title compounds were synthesized from a readily available steroidal acetylene by a protocol employing selenosulfonation, introduction of the appropriate side chain at C-24 via an alkyl selenocuprate, and reductive desulfonylation.

Full text of DOI:10.1016/S0040-4039(00)84483-4

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