Total synthesis of (15S, 16R, 19S, 20R, 34S)-diepomuricanin

DOI: 10.1016/0040-4039(96)01086-6

Source and publish data:

Tetrahedron Letters p. 5393 - 5396 (1996)

Update date:2022-07-30

Topics:

Authors:

Konno, Hiroyuki

Makabe, Hidefumi

Tanaka, Akira

Oritani, Takayuki

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Article abstract of DOI:10.1016/0040-4039(96)01086-6

An eleven-step reaction sequencing starting from enantiomerically pure (-)-muricatacin (6) afforded the key intermediate 12, which was then converted to (15S, 16R, 19S, 20R, 34S)-diepomuricanin (1) via introduction of an acetylene unit and a coupling reaction with iodo lactone synthon 15.

Full text of DOI:10.1016/0040-4039(96)01086-6

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