Tetrahedron Letters p. 5393 - 5396 (1996)
Update date:2022-07-30
Topics:
Konno, Hiroyuki
Makabe, Hidefumi
Tanaka, Akira
Oritani, Takayuki
An eleven-step reaction sequencing starting from enantiomerically pure (-)-muricatacin (6) afforded the key intermediate 12, which was then converted to (15S, 16R, 19S, 20R, 34S)-diepomuricanin (1) via introduction of an acetylene unit and a coupling reaction with iodo lactone synthon 15.
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