Unusually Coordinated Phosphorus Compounds; 7. Adamant-1-ylmethylidynephosphine, A New, Stable Phosphaalkyne

DOI: 10.1055/s-1986-31467

Source and publish data:

Synthesis p. 31 - 36 (1986)

Update date:2022-07-31

Topics:

Authors:

Allspach, T.

Regitz, M.

Becker, G.

Becker, W.

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Article abstract of DOI:10.1055/s-1986-31467

The reaction of trisphosphine (4a) as well as of the lithium bisphosphide*2 tetrahydrofuran complex (4b) with 1-adamantoyl chloride (5) results in the formation of the phosphaalkene 7 in 67percent or 96percent yield, respec

Full text of DOI:10.1055/s-1986-31467

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Product name:5-(Adamant-1-yl)-3-benzoyl-1H-1,2,4-diazaphosphole

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