Bulletin of the Chemical Society of Japan p. 503 - 506 (1986)
Update date:2022-08-03
Topics:
Kobayashi, Michio
Ohkubo, Hiromi
Shimizu, Toshio
An effective synthesis of selenoxides by the oxidation of selenides with t-butyl hypochlorite in the presence of methanol and pyridine followed by hydrolysis is described.This oxidation method is particularly effective for the oxidation of selenides which possess electron-withdrawing groups.A synthesis of partially optically active selenoxide with bulky substituents can be achieved using a novel oxidation method.
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