Reactivity of Ruthenium Polyhydrides: Reactions of RuH62 with C5-Cyclic Hydrocarbons. Preparation of New Ruthenium(IV)Trihydrides RuH3(C5Me5)L

DOI: 10.1039/c39860000985

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 985 - 986 (1986)

Update date:2022-08-03

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Authors:

Arliguie, Therese

Chaudret, Bruno

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Article abstract of DOI:10.1039/c39860000985

The hydrides RuH2(C5H6)(Pcy3)2 (2) and RuH(C5H5)(Pcy3)2 (3) (cy = cyclohexyl) are formed in the reaction of RuH6(Pcy3)2 (1) with cyclopentene, although in the presence of 3,3-dimethylbut-1-ene only (3) is formed quantitatively, but treatment of (1) with C

Full text of DOI:10.1039/c39860000985

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