
Journal of Organic Chemistry p. 5036 - 5038 (1986)
Update date:2022-08-02
Topics:
Padwa, Albert
Wisnieff, Thomas J.
Walsh, Edward J.
The reaction of α-diazo ketones derived from furanyl and benzofuranyl propionic acids with rhodium(II) acetate leads to cycloalkenones in high yield.Mechanistically,, the reaction involves addition of the keto carbene to the furanyl ?-bond followed by ele
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