PHOTOCHEMICAL AMINATION OF TETRACYANOBENZENE WITH ACETONITRILE IN THE PRESENCE OF ALIPHATIC AMINE

DOI: 10.1246/cl.1986.361

Source and publish data:

Chemistry Letters p. 361 - 364 (1986)

Update date:2022-07-30

Topics:

Authors:

Yamada, Shuzo

Nakagawa, Yoshiki

Watabiki, Oserojoin

Suzuki, Shin-ichi

Ohashi, Mamoru

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Article abstract of DOI:10.1246/cl.1986.361

Irradiation of dicyanoxylenes and dicyanodurene in acetonitrile in the presence of triethylamine gave mainly substitution and reduction products respectively, whereas a photochemical reaction of 1,2,4,5-tetracyanobenzene in the presence of N-methylpyrrolidine or nicotine gave tricyanoaniline, an amination product, as well as substitution products.

Full text of DOI:10.1246/cl.1986.361

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