Chemistry Letters p. 221 - 224 (1986)
Update date:2022-07-29
Topics: Conjugate addition Diastereomers Silyl enol ether Trityl perchlorate Aldol addition Tetrahydropyran Trifluoroacetic acid Triethylsilane Facile Method Stereoselective Syntheses
Kobayashi, Shu
Mukaiyama, Teruaki
In the presence of a catalytic amount of trityl perchlorate, the intermediate adducts, produced in situ by the conjugate addition of silyl enol ethers with α,β-unsaturated ketones, react with aldehydes to give the corresponding γ-acyl substituted δ-hydrox
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